翻訳と辞書 Words near each other ・ McFadden & Whitehead ・ McFadden & Whitehead (album) ・ McFadden (surname) ・ McFadden Act ・ McFadden House ・ McFadden Newell ・ McFadden's Flats ・ McFadden's Flats (1935 film) ・ McFaddin ・ McFaddin and Texas Point National Wildlife Refuges ・ McFaddin, Texas ・ McFaddin-Ward House ・ McFadyean ・ McFadyen ・ McFadyen (surname) ・ McFadyen–Stevens reaction ・ McFadzean ・ McFall ・ McFall House ・ McFall v. Shimp ・ McFall, Missouri ・ McFarlan ・ McFarlan Automobile ・ McFarlan Precinct, Hardin County, Illinois ・ McFarlan, North Carolina ・ McFarland ・ McFarland & Company ・ McFarland (surname) ・ McFarland baronets ・ McFarland Carillon Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク McFadyen–Stevens reaction ： ウィキペディア英語版 McFadyen–Stevens reaction The McFadyen–Stevens reaction is a chemical reaction best described as a base-catalyzed thermal decomposition of acylsulfonylhydrazides to aldehydes. Dudman ''et al.'' have developed an alternative hydrazide reagent. ==Reaction mechanism== The mechanism of the McFadyen–Stevens reaction is still under investigation. Two groups have independently proposed a heterolytic fragmentation mechanism. The mechanism involves the deprotonation of the acyl sulfonamide followed by a 1,2-hydride migration to give the alkoxide (3). The collapse of the alkoxide results in the fragmentation producing the desired aldehyde (4), nitrogen gas, and an aryl sulfinate ion (5). Martin ''et al.'' have proposed a different mechanism involving an acyl nitrene. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「McFadyen–Stevens reaction」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.